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Organic Polymer Chemistry

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This book deals with the organic chemistry of polymers which find technological use as adhesives, fibres, paints, plastics and rubbers. For the most part, only polymers which are of commercial significance are considered and the primary aim of the book is to relate theoretical aspects to industrial practice. The book is mainly intended for use by students in technical institutions and universities who are specializing in polymer science and by graduates who require an introduction to this field. Several excellent books have recently appeared dealing with the physical chemistry of polymers but the organic chemistry of polymers has not received so much attention. In recognition of this situation and because the two aspects of polymer chemistry are often taught separately, this book deals specifically with organic chemistry and topics of physical chemistry have been omitted. Also, in this way the book has been kept to a reasonable size. This is not to say that integration of the two areas of polymer science is undesirable; on the contrary, it is of the utmost importance that the inter-relationship should b~ appreciated. I wish to record my thanks to my colleagues with whom I have had many helpful discussions, particularly Mrs S. L. Radchenko. I also thank Miss E. Friesen for obtaining many books and articles on my behalf and Mr H. Harms for encouragement and assistance. I am also grateful to Mrs M. Stevens who skilfully prepared the manuscript. Department of Chemical and Metallurgical Technology, Ryerson Polytechnical Institute, K. J. S.
Category: Technology. ISBN: 9780412105807

Organic Fluorine Chemistry

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The present book is essentially based on the lectures on the chemistry of organic compounds of fluorine that I gave in 1969 at Virginia Polytechnic Institute in Blacksburg, Virginia, as a graduate course. References to material published to the end of 1969 are included. The book is primarily meant to provide the background for such a course, and, at the same time, to be a brief survey of recent knowledge in, and an introduction to deeper study of, this area of chemistry, which has been treated in a number of com prehensive monographs. I would like to thank Professor S. C. Cohen, Syracuse University, for the compilation of the data on mass spectra and nuclear magnetic res onance spectra, and my son, Tomas Hudlicky, and my daughter, Eva Hudlickci, for their help with the indexes. MILOS HUDLICKY February 13, 1970 Virginia Polytechnic Institute and State University Blacksburg, Virginia vii Contents CHAPTER 1. Introduction ......................................................... 1 Development of Fluorine Chemistry ......................................... .
Category: Science. ISBN: 9780306304880

Foundations of Organic Chemistry

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This book differs from other organic chemistry textbooks in that it is not focused purely on the needs of students studying premed, but rather for all students studying organic chemistry. It directs the reader to question present assumptions rather than to accept what is told, so the second chapter is largely devoted to spectroscopy (rather than finding it much later on as with most current organic chemistry textbooks). Additionally, after an introduction to spectroscopy, thermodynamics and kinetics, the presentation of structural information of compounds and organic families advances from hydrocarbons to alcohols to aldehydes and ketones and, finally, to carboxylic acids.
Category: Science. ISBN: 9780470479087

Organic Chemistry Study Guide

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Organic Chemistry Study Guide: Key Concepts, Problems, and Solutions features hundreds of problems from the companion book, Organic Chemistry , and includes solutions for every problem. Key concept summaries reinforce critical material from the primary book and enhance mastery of this complex subject. Organic chemistry is a constantly evolving field that has great relevance for all scientists, not just chemists. For chemical engineers, understanding the properties of organic molecules and how reactions occur is critically important to understanding the processes in an industrial plant. For biologists and health professionals, it is essential because nearly all of biochemistry springs from organic chemistry. Additionally, all scientists can benefit from improved critical thinking and problem-solving skills that are developed from the study of organic chemistry. Organic chemistry, like any "skill", is best learned by doing. It is difficult to learn by rote memorization, and true understanding comes only from concentrated reading, and working as many problems as possible. In fact, problem sets are the best way to ensure that concepts are not only well understood, but can also be applied to real-world problems in the work place. Helps readers learn to categorize, analyze, and solve organic chemistry problems at all levels of difficulty Hundreds of fully-worked practice problems, all with solutions Key concept summaries for every chapter reinforces core content from the companion book
Category: Science. ISBN: 9780128018897

Organic Chemistry for Babies

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Simple explanations of complex ideas for your future genius! Written by an expert, Organic Chemistry for Babies is a colorfully simple introduction to the structure of organic, carbon-containing compounds and materials. Babies (and grownups!) be one step ahead of pre-med students. Co-written by Cara Florance, who has a PhD in Biochemistry and a BS in Chemistry with work experience in astrobiololgy and radiation decontamination. With a tongue-in-cheek approach that adults will love, this installment of the Baby University board book series is the perfect way to introduce basic concepts to even the youngest scientists. After all, it's never too early to become a scientist! Baby University: It only takes a small spark to ignite a child's mind.
Category: Juvenile Nonfiction. ISBN: 9781492671169

Experimental Organic Chemistry

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The definitive guide to the principles and practice of experimental organic chemistry - fully updated and now featuring more than 100 experiments The latest edition of this popular guide to experimental organic chemistry takes students from their first day in the laboratory right through to complex research procedures. All sections have been updated to reflect new techniques, equipment and technologies, and the text has been revised with an even sharper focus on practical skills and procedures. The first half of the book is devoted to safe laboratory practice as well as purification and analytical techniques; particularly spectroscopic analysis. The second half contains step-by-step experimental procedures, each one illustrating a basic principle, or important reaction type. Tried and tested over almost three decades, over 100 validated experiments are graded according to their complexity and all are chosen to highlight important chemical transformations and to teach key experimental skills. New sections cover updated health and safety guidelines, additional spectroscopic techniques, electronic notebooks and record keeping, and techniques, such as semi-automated chromatography and enabling technologies such as the use of microwave and flow chemistry. New experiments include transition metal-catalysed cross-coupling, organocatalysis, asymmetric synthesis, flow chemistry, and microwave-assisted synthesis. Key aspects of this third edition include: Detailed descriptions of the correct use of common apparatus used in the organic laboratory Outlines of practical skills that all chemistry students must learn Highlights of aspects of health and safety in the laboratory, both in the first section and throughout the experimental procedures Four new sections reflecting advances in techniques and technologies, from electronic databases and information retrieval to semi-automated chromatography More than 100 validated experiments of graded complexity from introductory to research level A user-friendly experiment directory An instructor manual and PowerPoint slides of the figures in the book available on a companion website A comprehensive guide to contemporary organic chemistry laboratory principles, procedures, protocols, tools and techniques,  Experimental Organic Chemistry, Third Edition  is both an essential laboratory textbook for students of chemistry at all levels, and a handy bench reference for experienced chemists. 
Category: Science. ISBN: 9781119952381

Organic Chemistry, Volume One

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Volume I of this two-part series provides thorough coverage of aliphatic compounds, devoting 500 pages to their physical properties and various methods of synthetic preparation. It also discusses alicyclic compounds and their reactions, isomers, and processes. 1951 edition.
Category: Science. ISBN: 9780486607009

Advanced Organic Chemistry

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of Part A.- 1. Chemical Bonding and Molecular Structure.- 1.1. Valence-Bond Approach to Chemical Bonding.- 1.2. Bond Energies, Lengths, and Dipoles.- 1.3. Molecular Orbital Theory.- 1.4. Hckel Molecular Orbital Theory.- General References.- Problems.- 2. Stereochemical Principles.- 2.1. Enantiomeric Relationships.- 2.2. Diastereomeric Relationships.- 2.3. Dynamic Stereochemistry.- 2.4. Prochiral Relationships.- General References.- Problems.- 3. Conformational and Other Steric Effects.- 3.1. Steric Strain and Molecular Mechanics.- 3.2. Conformations of Acyclic Molecules.- 3.3. Conformations of Cyclohexane Derivatives.- 3.4. Carbocyclic Rings Other Than Six-Membered.- 3.5. Heterocyclic Conformational Analysis.- 3.6. Molecular Orbital Methods Applied to Conformational Analysis.- 3.7. Conformational Effects on Reactivity.- 3.8. Other Steric Effects on Reactivity.- General References.- Problems.- 4. Study and Description of Organic Reaction Mechanisms.- 4.1. Thermodynamic Data.- 4.2. Kinetic Data.- 4.3. Substituent Effects and Linear Free-Energy Relationships.- 4.4. Isotope Effects.- 4.5. Characterization of Reaction Intermediates.- 4.6. Catalysis.- 4.7. Solvent Effects.- 4.8.Basic Mechanistic Concepts: Kinetic Versus Thermodynamic Control, Hammond's Postulate, the Curtin-Hammett Principle.- 4.9. Isotopes in Labeling Experiments.- 4.10. Stereochemistry.- General References.- Problems.- 5. Nucleophilic Substitution.- 5.1. The Limiting CasesSubstitution by the Ionization (SN1) Mechanism.- 5.2. The Limiting CasesSubstitution by the Direct Displacement (SN2) Mechanism.- 5.3. Alternative Mechanistic Hypotheses.- 5.4. Carbonium Ions.- 5.5. Nucleophilicity.- 5.6. Leaving-Group Effects.- 5.7. Steric and Other Substituent Effects on Substitution and Ionization Rates.- 5.8. Stereochemistry of Nucleophilic Substitution.- 5.9. Secondary Kinetic Isotope Effects in Substitution Mechanisms.- 5.10. Neighboring-Group Participation.- 5.11. Carbonium Ion Rearrangements.- 5.12. Nonclassical Carbonium Ions and the Norbornyl Cation Problem.- 5.13. Synthetic Applications of Nucleophilic Substitution Reactions.- General References.- Problems.- 6. Polar Addition and Elimination Reactions.- 6.1. Addition of Hydrogen Halides to Alkenes.- 6.2. Acid-Catalyzed Hydration of Alkenes.- 6.3. Addition of Halogens.- 6.4. The E2, E1, and Elcb Mechanisms.- 6.5. Orientation Effects in Elimination Reactions.- 6.6. Stereochemistry of E2 Elimination Reactions.- 6.7. Dehydration of Alcohols.- 6.8. Eliminations Not Involving C-H Bonds.- General References.- Problems.- 7. Carbanions and Other Nucleophilic Carbon Species.- 7.1. Acidity of Hydrocarbons.- 7.2. Carbanions Stabilized by Functional Groups.- 7.3. Enols and Enamines.- General References.- Problems.- 8. Reactions of Carbonyl Compounds.- 8.1. Hydration and Addition of Alcohols to Aldehydes and Ketones.- 8.2. Addition-Elimination Reactions of Ketones and Aldehydes.- 8.3. Reactivity of Carbonyl Compounds toward Addition.- 8.4. Ester
Category: Science. ISBN: 9780306351167

Organic Quantum Chemistry Problems

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This collection of examples of the application of quantum chemical methods in the study of various chemical problems (main ly in organic chemistry) arose from an arrangement of the ma terials used by the first of the authors in his lectures on organic quantum chemistry and chemical constitution, delivered since 1959 at the Science Department of the Charles University, as well as in courses of quantum chemistry and, finally, in his lectures on the fundamentals of quantum chemistry held in the years 1965-1967 at the universities of Wiirzburg, Groningen, and Giessen, and at the Technical University of Darmstadt. This collection is to be regarded as a supplement to exist ing textbooks on organic quantum chemistry. Whereas the situa tion is satisfactory as far as the number and the standard of text books and monographs in this field are concerned, this cannot be 1 4 said of the collections of examples. Although in some books - a certain number of examples are presented, we believe, in view of the great importance of numerical calculations, that a separate publication of examples would be useful. A similar subject has 5 been dealt with in the recently published book by A. and 0. Julg and in the first part of a trilogy to be published by Heilbronner 6 and Bock.
Category: Science. ISBN: 9780306305160

Keynotes in Organic Chemistry

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This concise and accessible book provides organic chemistry notes for students studying chemistry and related courses at undergraduate level, covering core organic chemistry in a format ideal for learning and rapid revision. The material is organised so that fundamental concepts are introduced early, then built on to provide an overview of the essentials of functional group chemistry and reactivity, leading the student to a solid understanding of the basics of organic chemistry. Graphical presentation of information is central to the book, to facilitate the rapid assimilation, understanding and recall of critical concepts, facts and definitions. Students wanting a comprehensive and accessible overview of organic chemistry to build the necessary foundations for a more detailed study will find this book an ideal source of the information they require. In addition, the structured presentation, highly graphical nature of the text and practice problems with outline answers will provide an invaluable framework and aid to revision for students preparing for examinations. Keynotes in Organic Chemistry is also a handy desk reference for advanced students, postgraduates and researchers. For this second edition the text has been completely revised and updated. Colour has been introduced to clarify aspects of reaction mechanisms, and new margin notes to emphasise the links between different topics. The number of problems have been doubled to approximately 100, and includes spectra interpretation problems. Each chapter now starts with diagrams to illustrate the key points, and ends with a list of key reactions and a worked example.
Category: Science. ISBN: 9781119999140
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